THE UNITED REPUBLIC OF TANZANIA NATIONAL EXAMINATIONS COUNCIL CERTIFICATE OF SECONDARY EDUCATION EXAMINATION
032/1 CHEMISTRY 1
(For School Candidates Only)
TIME: 3 Hours Thursday, 7th October 2010 p.m.
Instructions
1. This paper consists of sections A, B and C.
2. Answer all questions in sections A and B, and two (2) questions from section C.
3. Calculators and cellular phones are not allowed in the examination room.
4. Write your Examination Number on every page of your answer booklet(s).
5. The following constants may be used:
Atomic masses: H = 1, O = 16, Na = 23, Mg = 24, C = 12
Cl = 35.5, K = 39, Pb = 207.
Avogadro’s number = 6.02 x 103 23.
GMV at s.t.p. = 22.4 dm .
1 Faraday = 96,500 coulombs.
Standard pressure = 760 mm Hg.
Standard temperature = 273 K.
1 litre = 1 dm3 = 1000 cm3.
.SECTION A (20 marks)
Answer all questions in this section.
1. For each of the items (i) (x), choose the correct answer among the given alternatives and write its letter beside the item number in the answer booklet provided.
(i) 1.4 g of potassium hydroxide is dissolved in water to form 250 cm3 of solution. What is the molarity of this solution?
(ii) In the blast furnace carbon monoxide is prepared by passing carbon dioxide over a redhot coke. Carbon dioxide is
(iii) A catalyst can be described as a substance
(iv) A covalent bond is formed when
(v) A solvent can be obtained from a solution by
(vi) Aqueous sugar solution is a poor conductor of electricity because
(vii) The process of giving away water of crystallization to the atmosphere by a chemical substance is called
(viii) Copper can be separated from a mixture of zinc and copper by adding to the mixture
(ix) Among the factors that determine the ions to be discharged at electrodes when salt solutions are electrolysed are their
(x) The mass of sodium hydroxide contained in 25 cm3 of 0.1 M NaOH is
2. Match the items in LIST A with the responses in LIST B by writing the letter of the correct response beside the item number.
LIST A | LIST B |
(i) Oxygen (ii) Sulphur dioxide (iii) Ammonia (iv) Hydrogen Chloride (v) Carbon monoxide (vi) Nitrogen (vii) Hydrogen (viii) Chlorine (ix) Nitrogen dioxide (x) Carbon dioxide |
|
SECTION B (60 marks)
Answer all questions in this section.
3. (a) Asubuhi Njema’s child was sick. When she took her to the hospital, she was prescribed some medicine including a bottle of syrup. The bottle was written, Shake before you use. What does this statement signify? (3 marks)
View Ans(b) (i) What is the first step to take when you want to identify the contents of a given salt containing one anion and one cation?
(ii) In a solution of water, identify a solute and a solvent. Justify your answer. (4 marks)
View Ans(c) Sodium is a solid while chlorine is a gas at room temperature although they are in the same period in the periodic table. What is the cause of this difference? (3 marks)
View Ans4. (a) Draw a well labeled diagram of a nonluminous Bunsen burner flame (3 marks)
View Ans(b) Explain the meaning of the following:
(i) Malleable
(ii) Ductile
(iii) Brittle (3 marks)
View Ans(c) Give an account of the following
(i) Anhydrous copper (II) sulphate becomes coloured when exposed to the air for a long time.
(ii) Carbon dioxide can be collected by the downward delivery method.
(iii) Concentrated sulphuric acid is not used for drying hydrogen sulphide gas.
(iv) Sodium metal is kept in paraffin oil. (4 marks)
View Ans5. (a) Classify the following reactions into oxidation and reduction reactions.
(i) S( s) + O 2( g) ? SO 2( g)
(ii) N2( g) + 3H 2( g) ? 2NH 3( g)
(iii) Fe2+ (aq) e ? Fe3+ (aq)
(iv) Fe3+ (aq) e ? Fe2+ (aq) (4 marks)
View Ans(b) What is the oxidation number of iron in iron (III) chloride? (3 marks)
View Ans(c) In the following reaction, name a reducing agent substance and an oxidizing agent:
CuO( s) + H 2( g) ? Cu ( s) + H 2 O ( g) (3 marks)
View Ans6. (a) Which homologous series of organic compounds can be represented by the following general formula?
(i) Cn H2n+2
(ii) CnH2n
(iii) Cn H2 n+1OH (3 marks)
View Ans(b) Give the name of the first compound in each series. (3 marks)
View Ans(c) (i) Describe a reaction by which a named compound of series in (a) (ii) can be converted to a compound of series in (a) (ii).
(ii) How can a compound of series (a) (iii) be converted to a compound of series in (a) (ii)? (4 marks)
View Ans7. (a) Differentiate empirical formula from molecular formula. (2 marks)
View Ans(b) Calculate the percentage composition by mass of water in a hydrated magnesium chloride MgCl2•6H 2O. (3 marks)
View Ans(c) Calculate the empirical formula for a compound with the following composition: lead 8.32 g, sulphur 1.28 g, oxygen 2.56 g (relative atomic wt of lead = 207, sulphur = 32, oxygen = 16) (5 marks)
View Ans8. (a) Ammonia gas can be prepared by heating an ammonium salt with an alkali
(i) Name the most common pair of reagents suitable for this reaction.
(ii) Write the equation for the reaction. (4 marks)
View Ans(b) Ammonia is very soluble in water and less dense than air. How does each of the properties determine the way in which ammonia is collected in a gas jar? (4 marks)
View Ans(c) Give reasons for the following:
(i) Solution of chlorine in water is acidic
(ii) Yellow phosphorus is stored under water.
View AnsSECTION C (20 marks)
Answer all questions from this section.
9. (a) (i) What are the natural causes of soil acidity?
(ii) What cations prevail in acidic soils? (2 marks)
View Ans(b) (i) On treatment with calcium hydroxide the soil pH was raised from 5 to 7.
What can you say about the properties of calcium hydroxide?
(ii) What effects can the alkalinity of a soil have on the availability of nutrients?
(iii) Is it sensible to add lime to a field which has received an application of
ammonium sulphate fertilizer? Explain. (5 marks)
View Ans(c) Which reference to pH, solubility and any other factors, list the main properties of the following fertilizers used in our country:
(i) Ammonium sulphate
(ii) Super phosphate
(iii) Urea (3 marks)
View Ans10. (a) (i) State Avogadro’s law of gaseous volume.
(ii) Find the volume of oxygen gas required to burn completely 1 dm3 of methane. CH4 + 2O 2(g) ? CO 2 + 2H 2O.
(iii) What is the volume of carbon dioxide formed in the reaction at (ii) (4 marks)
(b) Define the following terms: (i) Mole (ii) Molecular weight (2 marks) (c) Calculate the total number of (i) molecules in 0.18g of water (ii) electrons present in 0.0001 moles of pure magnesium metal (4 marks) 11. (a) Elements A, B, C and D have atomic numbers 6, 8, 17 and 20 respectively. Write electronic structures of these elements. (4 marks) (b) Write down the formulae of the simplest compounds you would expect when (i) A and B combine chemically (ii) C and D combine chemically. (2 marks) (c) (i) What types of bonding you would expect to occur in each of the compounds formed in (b) (ii) List three (3) differences in properties you would expect to find between the compounds in (i) as a result of their difference in types of bonding. (4 marks) 12. Read the following information carefully then answer questions that follow: 25 cm3 of potassium hydroxide were placed in a flask and a few drops of phenolphthalein indicator were added. Dilute hydrochloric acid was added until the indicator changed colour. It was found that 21 cm3 of acid were used. (b) (i) What piece of apparatus should be used to measure out accurately 25 cm3 of sodium hydroxide solution? (ii) What colour was the solution in the flask at the start of the titration? (iii) What colour did it turn when the alkali had been neutralized? (3 marks) (c) (i) Was the acid more concentrated or less concentrated than the alkali? Give reasons for your answer. (ii) Name the salt formed in the neutralization. (iii) Write an equation for the reaction. (4 marks) (d) Utilizing the given information describe how you can obtain pure crystals of the salt. (3 marks)